Spider-Man - Season 1 (1967), Episode 14: Horn of the Rhino

Trailer

Sick with a cold, Spiderman must battle the Rhino, a powerful, horned villain capable of ramming through trains, trucks, and submarines. Though Peter's Aunt May forbids her ailing nephew to procure pictures for Jameson of the Rhino's wrath, Peter leaves his bed to become Spiderman each time that a component to a top-secret military weapon is due to arrive in New York City, because the Rhino wants the weapon and will stop at nothing to steal the components, three in total, coming to New York by train, airplane, and submarine. But the sneezing Spidey is unable to stop the Rhino from snatching the components. Finally, as the Rhino is assembling the weapon from the three heisted components, Spidey obtains a can of pepper from Aunt May's cupboard, finds the Rhino's hideout, a cave at the New York City Zoo, and webs the can of pepper onto the Rhino's horn, which punctures the can, and pepper drops in the Rhino's face so that the Rhino now too has a sneezing handicap. An avalanche of mud falls upon the Rhino, and Spidey bakes the mud with a heat ray to trap the horned criminal, then gains possession of the weapon to return it to the military. The Rhino is apprehended by the NYPD, and Peter confines himself to bed to allow Aunt May to fully treat his cold.

Genre: Action, Adventure, Animation